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A borane laser

delete2015-01-13
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OA
AI
L
Luis Cerdán
J
Jakub Braborec
I
Inmaculada García‐Moreno
Á
Á. Costela
M
Michael G. S. Londesborough *
DOI:10.1038/ncomms6958delete
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摘要

摘要

En 中文
Emission from electronically excited species forms the basis for an important class of light sources-lasers. So far, commercially available solution-processed blue-emitting laser materials are based on organic compounds or semiconductor nanocrystals that have significant limitations: either low solubility, low chemical- and/or photo-stability and/or uncompetitive prices. Here we report a novel and competitive alternative to these existing laser materials that is based on boron hydrides, inorganic cluster compounds with a rich and diverse chemistry. We demonstrate that solutions of the borane anti-B18H22 show, under pulsed excitation, blue laser emission at 406 nm with an efficiency (ratio of output/input energies) of 9.5%, and a photostability superior to many of the commercially available state-of-the-art blue laser dyes. This demonstration opens the doors for the development of a whole new class of laser materials based on a previously untapped resource for laser technology-the boranes.
Keyword:
B18H22
BLUE
MOLECULES
EMISSION
CLUSTER
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Nature Communications 封面图
Nature Communications
IF:
15.7
论文数:
9.4W
被引数:
91.2W

机构

C
consejo superior de investigaciones cientificas (csic)
学者数:
8.8W
论文数: 8.5W
被引数: 125
C
csic - instituto de quimica fisica rocasolano (iqfr)
学者数:
291
论文数: 145
被引数: 0
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