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A borane laser
DOI:10.1038/ncomms6958.png)
摘要
En 中文
Emission from electronically excited species forms the basis for an important class of light sources-lasers. So far, commercially available solution-processed blue-emitting laser materials are based on organic compounds or semiconductor nanocrystals that have significant limitations: either low solubility, low chemical- and/or photo-stability and/or uncompetitive prices. Here we report a novel and competitive alternative to these existing laser materials that is based on boron hydrides, inorganic cluster compounds with a rich and diverse chemistry. We demonstrate that solutions of the borane anti-B18H22 show, under pulsed excitation, blue laser emission at 406 nm with an efficiency (ratio of output/input energies) of 9.5%, and a photostability superior to many of the commercially available state-of-the-art blue laser dyes. This demonstration opens the doors for the development of a whole new class of laser materials based on a previously untapped resource for laser technology-the boranes.
Keyword:
B18H22
BLUE
MOLECULES
EMISSION
CLUSTER
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期刊
IF:
15.7
论文数:
9.4W
被引数:
91.2W
机构
引用论文
Carboranethiol-modified gold surfaces.: A study and comparison of modified cluster and flat surfaces
LANGMUIR
IF3.9

