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A ceramic/polymer composite solid electrolyte for sodium batteries
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DOI：10.1039/c6ta07590h.png)
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摘要
En 中文
Achieving high ionic conductivity in solid electrolytes and reducing the interfacial resistance between solid electrolytes and electrode materials are considered to be one of the biggest challenges in developing solid-state batteries. The integration of the high ionic conductivity of inorganic ceramics and the flexibility of organic polymers was attempted to yield a solvent-free ceramic/polymer composite solid electrolyte for Na batteries for the first time. The composite solid electrolytes exhibit a Na+ ion conductivity as high as 2.4 mS cm(-1) at 80 degrees C. Meanwhile, this composite membrane is thermally stable up to 150 degrees C and maintains the flexibility of polymer electrolytes. The solid-state Na3V2(PO4)(3)/CPE/Na battery using this ceramic/polymer composite electrolyte exhibits an initial reversible capacity of 106.1 mA h g(-1) and excellent cycle performance with negligible capacity loss over 120 cycles.
Keyword:
ION BATTERIES
RECHARGEABLE BATTERIES
LITHIUM
CHALLENGES
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期刊
IF:
9.5
论文数:
3.3W
被引数:
21.7W
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