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A comparative theoretical study on the photoisomerization and antioxidant capacity of resveratrol and its Azo/Dihydro analogs
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DOI：10.1016/j.jphotobiol.2025.113251.png)
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Abstract
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• Establishes design principles for photo-responsive antioxidants by tuning skeleton, stereochemistry, and electronic state. • Azo-substitution promotes photoisomerization and enhances antioxidant activity. • Excited-state cis-isomers identified as superior radical scavengers. • Photoexcitation universally boosts antioxidant potential via reduced ionization potential.
Keywords:
photo-responsive antioxidants
azo-substitution
photoisomerization
excited-state
radical scavenging
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