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A minimal electrostatic theory for the Seebeck coefficient in liquids
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DOI：10.1016/j.molliq.2026.129850.png)
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Abstract
En 中文
• A minimal electrostatic theory is proposed for the Seebeck coefficient in liquids. • The extended Born model rationalizes the mV/K-scale solvation contribution in a cobalt redox electrolyte. • The first solvation shell is described by an apparent effective dielectric response. • Large ionic valence, small cation radius, low dielectric constant, and large d /dT enhance the liquid Seebeck response.
Keywords:
Thermoelectrics
Seebeck coefficient
Solvation entropy
Journal
IF:
5.2
Papers:
2.5W
Citations:
9.0W
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