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A room temperature spin crossover ionic liquid
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DOI：10.1039/c5dt04264j.png)
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摘要
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Two new paramagnetic ionic liquids (ILs) comprising a mononuclear iron(III) or manganese(III) complex cation, charge balanced by a dicyanamide anion are reported which show a range of spin states. Both are liquids at room temperature and the Fe(III) based IL exhibits a spin crossover close to 300 K. The spin crossover profile is independent of the solvation, and is both air and moisture stable.
Keyword:
MANGANESE(III) COMPLEX
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期刊
IF:
3.3
论文数:
3.3W
被引数:
8.0W
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