.png){kind=icon}
.png){kind=icon}
Return
A sinter-free future for solid-state battery designs
.png){kind=icon}
OA
AI
DOI：10.1039/d2ee00279e.png)
.png){kind=icon}
Original request for help.png){kind=icon}
Share.png){kind=icon}
Save
Abstract
En 中文
Ceramic-based solid electrolytes and separators are particularly attractive for use in next-generation batteries as a way to increase the electrochemical stability window and improve safety. However, batteries with higher energy densities require thin membranes comparable in thickness to the polymer separators (e.g., 10-25 mu m) found in today's Lithium-ion batteries. To date, conventional ceramic-electrolyte processing routes have not been able to achieve this goal as they typically operate on the principle of sintering: going from particle to a densified ceramic body. To overcome this challenge, we provide a blueprint for an alternative cost-effective sequential decomposition synthesis (SDS) approach that uniquely accesses the thickness range required from solid Li oxide-based electrolytes close to those of today's polymer separators and offers immense opportunities for to obtain the desired phase at significantly lower processing temperatures (<700 degrees C) with unique ceramic microstructures. We specifically highlight the SDS processing of Li garnets and disclose basic SDS precursor and ceramic processing concepts that can be adapted to other Li-containing oxides.
Keywords:
THIN-FILMS
ELECTROLYTE
CONDUCTIVITY
TEMPERATURE
DEPOSITION
STABILITY
Journal
IF:
30.8
Papers:
6.9K
Citations:
12.4W
Organization
No organization information available