返回
A solid polymer electrolyte for aluminum ion conduction
DOI:10.1016/j.rinp.2018.07.001.png)
摘要
En 中文
We report on the synthesis and characterization of a solid polymer electrolyte for aluminum ion conduction. The solid polymer electrolyte is produced via the copolymerization of a low molecular weight polytetrahydrofuran and a cycloaliphatic epoxy. The crosslinked copolymer is swollen in THF solutions of different concentrations of aluminum nitrate as the aluminum ion source. The conductivity as a function of concentration is measured via AC impedance spectroscopy over a temperature range of 20-110 degrees C. We attain conductivities that increase with salt loading, reaching a value of 2.86x10(-5) S.cm(-1). Thermogravimetric analysis shows the electrolytes are stable up to 150 degrees C. Raman spectroscopy reveals complete dissociation of the aluminum nitrate salt in the electrolyte over the concentration range explored. This study establishes a polymer system and synthetic route towards solid polymer electrolytes for aluminum ion conduction, for the development of all solid-state aluminum ion batteries.
Keyword:
Polymers
Electrolyte
Aluminum
Ion conduction
AI总结
对已上传原文的论文进行重点信息的提取,主要内容包括:简要概述、研究摘要、背景介绍、关键亮点、图文解析、展望与总结。
期刊
IF:
4.6
论文数:
440
被引数:
2.7W
机构
引用论文
The Compensation Effect in the Vogel-Tammann-Fulcher (VTF) Equation for Polymer-Based Electrolytes聚合物基电解质的vogel-tammann-fulcher (VTF) 方程中的补偿效应
MACROMOLECULES
IF5.2
Neuropsychology of subjects with ultra-high risk (UHR) of psychosis: A critical analysis of the literature
L'Encéphale
IF0
Single ion conducting sodium ion batteries enabled by a sodium ion exchanged poly(bis(4-carbonyl benzene sulfonyl)imide-co-2,5-diamino benzesulfonic acid) polymer electrolyte通过钠离子交换的聚 (双 (4-羰基苯磺酰基) imide-co-2,5-二氨基苯磺酸) 聚合物电解质实现的单离子传导钠离子电池
SOLID STATE IONICS
IF3.3
A porous gel-type composite membrane reinforced by nonwoven: promising polymer electrolyte with high performance for sodium ion batteries无纺布增强的多孔凝胶型复合膜: 用于钠离子电池的高性能聚合物电解质
ELECTROCHIMICA ACTA
IF5.6
Where in the brain is nonliteral language? A coordinate-based meta-analysis of functional magnetic resonance imaging studies
NeuroImage
IF0

