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Amidinate- and Dithiolene-Based Silicon Complexes

delete2025-03-19
delete0
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OA
AI
Y
Yuzhong Wang
J
Johnson, John C.
P
Palmer, Kayla G.
P
Pingrong Wei
E
Earle R. Adams
M
Mitchell E. Lahm
H
Henry F. Schaefer
G
Gregory H. Robinson *
DOI：10.1021/acs.organomet.5c00038delete
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摘要

摘要

En 中文
amidinato-硅烯氯化物 PhC( t BuN)2SiCl (1) 与咪唑基硫代二酮二聚体 2、锂二硫醇盐自由基 3 和二硫醇盐二聚体 4 的反应，分别合成了含酰胺基和二硫醇盐配体的系列硅配合物 5-7。7 是首个结构表征的硅(II)二硫醇盐配合物。5-7 的结构与成键特征已通过实验和理论方法进行了探究。
Keyword:
CATALYTIC-ACTIVITY
BIS(SILYLENE)
PHC(NTBU)(2)
ACTIVATION
REACTIVITY
LIGANDS

期刊

Organometallics 封面图
Organometallics
IF:
2.9
论文数:
611
被引数:
2.8W

机构

U
Univ Georgia
学者数:
1.2K
论文数: 614
被引数: 230
引用论文

引用论文

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A Stable Anionic Dithiolene Radical
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1,2-Dithiolate derivatives of monosilanes and disilanes
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Charge, bond order and valence in the AB initio SCF theory
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Amidinato silylene-based inorganic aromatic rings
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