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Apparent Increasing Lithium Diffusion Coefficient with Applied Current in Graphite

delete2020-08-27
delete39
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OA
AI
D
Dennis W. Dees *
M
Marco‐Tulio F. Rodrigues
K
Kaushik Kalaga
S
Stephen E. Trask
I
Ilya A. Shkrob
D
Daniel P. Abraham
A
Andrew N. Jansen
DOI:10.1149/1945-7111/abaf9fdelete
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摘要

摘要

En 中文
In this study, we assert that the apparent lithium diffusion coefficient in graphite active particles in the negative electrodes of lithium-ion cells increases appreciably with the intercalation rate. This assertion is based on an electrochemical model analysis of a wide range of electrochemical micro-reference electrode full cell studies on a coated natural graphite and other literature results. While the mechanism for this increase is a subject of further investigation, the results of our study suggest that the lithium transport in the graphite does not limit the maximum attainable charging rate in typical lithium-ion cells for electric vehicles.
Keyword:
lithium-ion battery
graphite electrode active material
lithium diffusion rate

期刊

Journal of the Electrochemical Society 封面图
Journal of the Electrochemical Society
IF:
3.3
论文数:
3.3W
被引数:
9.4W

机构

U
united states department of energy (doe)
学者数:
11.3W
论文数: 9.6W
被引数: 246
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