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Artificial Interphase Layer for Stabilized Zn Anodes: Progress and Prospects

delete2022-08-22
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PRE
AI
Q
Qihui Zhang
Y
Yiwen Su
Z
Zixiong Shi
杨先中 封面图
杨先中 (Xianzhong Yang)
孙竟毓 封面图
孙竟毓 (Jingyu Sun) *
DOI:10.1002/smll.202203583delete
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摘要

摘要

En 中文
The burgeoning Li-ion battery is regarded as a powerful energy storage system by virtue of its high energy density. However, inescapable issues concerning safety and cost aspects retard its prospect in certain application scenarios. Accordingly, strenuous efforts have been devoted to the development of the emerging aqueous Zn-ion battery (AZIB) as an alternative to inflammable organic batteries. In particular, the instability from the anode side severely impedes the commercialization of AZIB. Constructing an artificial interphase layer (AIL) has been widely employed as an effective strategy to stabilize the Zn anode. This review specializes in the state-of-the-art of AIL design for Zn anode protection, encompassing the preparation methods, mechanism investigations, and device performances based on the classification of functional materials. To begin with, the origins of Zn instability are interpreted from the perspective of electrical field, mass transfer, and nucleation process, followed by a comprehensive summary with respect to functions of AIL and its designing criteria. In the end, current challenges and future outlooks based upon theoretical and experimental considerations are included.
Keyword:
aqueous Zn-ion batteries
artificial interphase layers
latest research progress
Zn anodes

期刊

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Small
IF:
12.1
论文数:
3.1W
被引数:
16.4W

机构

S
soochow university - china
学者数:
5.2W
论文数: 3.6W
被引数: 82
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