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Artificial Processive Catalytic Systems
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DOI：10.1002/chem.202304230.png)
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摘要
En 中文
Processive catalysts remain attached to a substrate and perform multiple rounds of catalysis. They are abundant in nature. This review highlights artificial processive catalytic systems, which can be divided into (A) catalytic rings that move along a polymer chain, (B) catalytic pores that hold polymer chains and decompose them, (C) catalysts that remain attached to and move around a cyclic substrate via supramolecular interactions, and (D) anchored catalysts that remain in contact with a substrate via multiple catalytic interactions (see frontispiece). A processive catalyst undergoes several rounds of catalysis before it is released from the substrate. The drawing shows possible ways (A-D) in which a synthetic catalyst can interact with the substrate to achieve processivity. image
Keyword:
Supramolecular catalysis
rotaxanes
catalytic macrocycles
processive catalytic depolymerization
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期刊
C
IF:
3.7
论文数:
3.9W
被引数:
9.6W
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引用论文
Mechanistic Insights into Processive Polyethylene Hydrogenolysis through In Situ NMR.png)
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