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Atmospheric fate of ketolimonene part 1: temperature-dependent kinetics and gas-phase products from NO3-initiated oxidation
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DOI：10.1016/j.jes.2026.05.012.png)
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Abstract
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• Nighttime NO3 oxidation of ketolimonene is investigated. • Kinetics and products constrained using multiple highly instrumented chambers • Rate coefficients show negative temperature dependence over 273–353 K kketolimonene+NO3(293−353)=(1.48±0.65)×10−12exp[(556.7±26.5)T]cm3 molecule-1 s-1 • NO3 oxidation results in very short nighttime atmospheric lifetimes • Organic nitrates and HOMs reveal efficient autooxidation pathways
Keywords:
ketolimonene
NO3 oxidation
temperature-dependent kinetics
organic nitrates
autooxidation pathways
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