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Cation regulation on electro-synthesis of peroxydisulfate from sulfate-containing wastewater via outer-sphere pathway
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DOI:10.1016/j.jhazmat.2026.143095.png)
Abstract
En 中文
• Cations regulate outer-sphere PDS electrosynthesis via ·OH control, following K+ > NH4+ > Na+. • K+ lowers dehydration barrier for ·OH entry and delocalizes spin density, stabilizing ·OH to boost SO4-· formation. • K+ enhances PDS production from sulfate wastewater, offering a low-cost strategy than increasing concentration alone.
Journal
IF:
11.3
Papers:
3.9W
Citations:
24.0W
