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Co-pyrolysis of cow dung and spent mushroom substrate: Insight into synergistic mechanisms based on kinetic and 2D-PCIS analysis
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DOI：10.1016/j.jaap.2026.108004.png)
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Abstract
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• CD acts as a catalytic initiator in SMS co-pyrolysis, altering reaction pathways. • Co-pyrolysis enhanced the gas yield to 34.4 wt%, with an H2/CO ratio of 1.15(800 °C). • Catalytic synergy lowers the apparent activation energy for deep cracking by 18.1%. • 2D-PCIS proves CD amino acid cleavage induces early fracture of SMS C-O/CO bonds. • Co-pyrolysis eliminates unstable amines and enriches stable oxygenated compounds.
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