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Cobalt selectively annulates
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DOI：10.1038/s44160-022-00126-0.png)
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Making chiral molecules by C-H bond activation using inexpensive, earth-abundant metal catalysts is challenging. Now, a cobalt salt combined with a salicyl-oxazoline ligand enables a C-H activation and annulation process and the introduction of axial chirality around a C-N bond.
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分享收藏Atroposelective isoquinolinone synthesis through cobalt-catalysed C-H activation and annulation.png)
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分享收藏分享收藏Cobalt-Catalyzed, Aminoquinoline-Directed C(sp2)-H Bond Alkenylation by Alkynes钴催化的炔烃的氨基喹啉定向C(sp2)-H键烯基化
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