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Compositional Patterning in Carbon Implanted Titania Nanotubes

delete2021-07-03
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Astrid Kupferer *
A
Alexander Holm
A
Andriy Lotnyk
S
S. Mändl
S
S. G. Mayr *
DOI:10.1002/adfm.202104250delete
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摘要

摘要

En 中文
Ranging from novel solar cells to smart biosensors, titania nanotube arrays constitute a highly functional material for various applications. A promising route to modify material characteristics while preserving the amorphous nanotube structure is present when applying low-energy ion implantation. In this study, the interplay of phenomenological effects observed upon implantation of low fluences in the unique 3D structure is reported: sputtering versus readsorption and plastic flow, amorphization versus crystallization and compositional patterning. Patterning within the oxygen and carbon subsystem is revealed using transmission electron microscopy. By applying a Cahn-Hilliard approach within the framework of driven alloys, characteristic length scales are derived and it is demonstrated that compositional patterning is expected on free enthalpy grounds, as predicted by density functional theory based ab initio calculations. Hence, an attractive material with increased conductivity for advanced devices is provided.
Keyword:
density functional theory calculations
driven alloys
mixing enthalpies
pattern formation
phase separation
titanium dioxide
transmission electron microscopy
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期刊

Advanced Functional Materials 封面图
Advanced Functional Materials
IF:
19
论文数:
3.5W
被引数:
32.1W

机构

L
Leipzig University
学者数:
2.0W
论文数: 1.6W
被引数: 17
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