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Concave hydrocarbons

delete2006-01-21
delete72
PRE
AI
J
Jens Groß
G
G. Harder
A
A. Siepen
J
J. Harren
F
Fritz Vögtle
H
Holger Stephan
K
Karsten Gloe
B
Benedikt Ahlers
K
Karl Cammann
K
Kari Rissanen
DOI：10.1002/chem.19960021218delete
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摘要

摘要

En 中文
Concave hydrocarbons, such as 1 (C36H36), 4 (C60H60), 5 (C54H48), and 6 (C60H52), represent three-dimensionally clamped analogues of pi-prismands. They encapsulate small metal ions and accomplish metal-ion extraction from aqueous solution. Their remarkable selectivity allows applications such as incorporation in ion-selective electrodes. The synthetic route is based on well-established cyclophane methodology and, thus, offers a general approach to a whole family of concave hydrocarbons.
Keyword:
concave hydrocarbons
cyclophanes
host/guest chemistry
ion-selective electrodes
prismands
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期刊

C
Chemistry-A European Journal
IF:
3.7
论文数:
3.9W
被引数:
9.6W

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