.png){kind=icon}
返回
Controlled/living radical polymerization: Features, developments, and perspectives
.png){kind=icon}
PRE
AI
DOI：10.1016/j.progpolymsci.2006.11.002.png)
.png){kind=icon}
原文求助.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
Recent mechanistic developments in the field of controlled/living radical polymerization (CRP) are reviewed. Particular emphasis is placed on structure-reactivity correlations and rules for catalyst selection in atom transfer radical polymerization (ATRP), for chain transfer agent selection in reversible addition-fragmentation chain transfer (RAFT) polymerization, and for the selection of an appropriate mediating agent in stable free radical polymerization (SFRP), including organic and transition metal persistent radicals. Novel methods of fine tuning initiation, activation, and deactivation processes for all techniques are discussed, including activators regenerated by electron transfer (ARGET) and initiators for continuous activator regeneration (ICAR) ATRP, whereby Cu catalyst concentrations in ATRP can be lowered to just 10 ppm. Progress made in each technique related to the synthesis of both high and low molecular weight polymers, end functional polymers, block copolymers, expanding the range of polymerizable monomers, synthesis of hybrid materials, environmental issues, and polymerization in aqueous media is thoroughly discussed and compared. (c) 2006 Elsevier Ltd. All rights reserved.
Keyword:
controlled/living radical polymerization
nitroxide-mediated polymerization (NMP)
stable free radical polymerization (SFRP)
atom transfer radical polymerization (ATRP)
degenerative transfer polymerization
reversible addition-fragmentation chain transfer (RAFT) polymerization
AI总结
对已上传原文的论文进行重点信息的提取，主要内容包括：简要概述、研究摘要、背景介绍、关键亮点、图文解析、展望与总结。
期刊
IF:
26.1
论文数:
1.4K
被引数:
3.0W
机构
暂无机构信息
引用论文
.png){kind=icon}
查看更多内容