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Crystal templating through liquid-liquid phase separation
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DOI：10.1039/c4cc07880b.png)
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摘要
En 中文
Controlled induction of crystal nucleation is a highly desirable but elusive goal. Attempts to speed up crystallization, such as high super saturation or working near a liquid-liquid critical point, always led to irregular and uncontrollable crystal growth. Here, we show that under highly nonequilibrium conditions of spinodal decomposition, water crystals grow as thin wires in a template-less formation of Haareis. This suggests that such nonequilibrium conditions may be employed more widely as mechanisms for crystal growth control.
Keyword:
CALCIUM-CARBONATE
NUCLEATION
CRYSTALLIZATION
CLUSTERS
TRANS-1,2-DICHLOROETHYLENE
PRESSURE
ICE
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期刊
IF:
4.2
论文数:
5.9W
被引数:
16.5W
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