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Deracemization in a solvent cage

delete2025-11-28
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PRE
AI
S
Subham Das
B
Basudev Sahoo *
DOI：10.1038/s41557-025-02002-8delete
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摘要

摘要

En 中文
外消旋混合物转化为单一对映异构体是高度期望但具有挑战性的。现在，一种光催化策略将溶剂笼内的均裂外消旋化转变为一种对映选择性消旋化逆转过程。通过不对称孪生再铸，实现了手性硫立体中心的定向构建。
Keyword:
Deracemization
Photocatalysis
Enantioselective synthesis
Solvent cage
Chiral sulfur stereocenters

期刊

Nature Chemistry 封面图
Nature Chemistry
IF:
20.2
论文数:
4.4K
被引数:
4.8W

机构

I
indian institute of science education and research
学者数:
488
论文数: 225
被引数: 0
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