Direct Propane Fuel Cell Anode with Interdigitated Flow Fields: Two-Dimensional Model

Hamidreza Khakdaman

doi:10.1021/ie900727p

Direct Propane Fuel Cell Anode with Interdigitated Flow Fields: Two-Dimensional Model

2010-02-03

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DOI：10.1021/ie900727p

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The first two-dimensional model of a direct propane fuel cell (DPFC) anode was developed and used to investigate materials and operating conditions that resulted in improved DPFC anode performance. The software used, FreeFEM++, is open Source and is based oil the finite element method. The anode catalyst layer (ACL) was composed of three phases. One solid phase was the platinum catalyst Supported oil porous carbon (an electron conductor). The second solid phase consisted of solid zirconium phosphate (a proton conductor at 150 degrees C). The gas phase was located within the pores of the carbon and between the solid particles. Operation at 150 degrees C allowed the propane gas phase concentration to be in direct contact with the catalyst at the entrance to the ACL. This was ail important advantage compared to previous DPFC operations at conditions where aqueous liquids are present (PEMFC at temperatures less than 100 degrees C and direct propane PAFC). When aqueous liquids Surround the catalyst, the propane concentration in contact with the catalyst at the ACL entrance is Much smaller because the Solubility of propane ill aqueous liquids is small. The one-third improvement ill the anode overpotential was attributed to this difference. By using interdigitated flow fields with the propane feed in one set of channels and the carbon dioxide product in another set of channels, there was no mixing or the two so that the maximum propane concentration was always present at the entrance to the ACL. The residence time Could be chosen, by adjusting the distance between the feed and the product channels (length of land Plus channel), to obtain large values of conversion and large values of fuel utilization. It was shown that the larger pressure drops often associated with interdigitated now fields compared to conventional serpentine flow fields were diminished by increasing the thickness of the catalyst layer. Ill addition, the thicker catalyst layer permitted the Pt catalyst to be spread over a greater thickness of carbon catalyst Support, thereby ensuring better catalyst dispersion and improved catalyst performance.

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ZIRCONIUM-PHOSPHATE

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Direct Propane Fuel Cell Anode with Interdigitated Flow Fields: Two-Dimensional Model

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