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Doping-driven swelling in low-temperature PEDOT:PSS films
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DOI：10.1016/j.electacta.2026.149691.png)
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Abstract
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• PEDOT:PSS films galvanostatically synthesised at 0 °C exhibits Na+ exchange. • In situ ellipsometry tracks redox-driven optical changes. • Applied methodology that allows to extract n, k, and thickness vs applied potential. • Reversible contraction/expansion with ∼200% swelling in reduction. • Potential cathode to offset anode volume changes in batteries.
Keywords:
PEDOT:PSS
Low temperature synthesis
Ellipsometry
Optical properties
Volume changes
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