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Double stranded interwound infinite linear silver coordination network
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DOI：10.1039/b103824a.png)
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摘要
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Upon self-assembly of a bismonodentate ligand based on two pyridine units interconnected at the para position by a hexaethylene glycol fragment using ester junctions and Ag+ cation, a double stranded interwound infinite linear network was obtained in the crystalline phase; the formation of this unprecedented architecture is a result of the loop type conformation of the connector segment which forms a pseudo-crown ether. The loop surounds the metal cation which is linearly coordinated to two pyridines belonging to consecutive units, thus forming the 1-D network.
Keyword:
STRUCTURAL-ANALYSIS
MOLECULAR TECTONICS
DESIGN
LIGAND
POLYMERS
CATION
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