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Dynamic ring-opening polymerization, D-ROP: Applications in coordination polymers
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DOI：10.1016/j.ccr.2021.214342.png)
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An account is given of progress over the past 20 years in dynamic ring opening polymerization, D-ROP. DROP is a form of self-assembly in which a metal ion is typically combined with a flexible bidentate ligand that may form either a macrocycle, a ring-opened oligomer or a polymer, with the polymer formed only during crystallization. This method has yielded coordination polymers with remarkably high selectivity, and the polymers can be designed with a wide arrange of additional functionality. This review outlines the principles, illustrated with selected examples, and outlines what is currently known about the mechanisms of the self-assembly. (c) 2021 Elsevier B.V. All rights reserved.
Keyword:
Dynamic
Ring-opening
Polymer
Coordination
Self-assembly
期刊
IF:
23.5
论文数:
9.4K
被引数:
7.3W
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