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Efficient and selective hydrogenation of biomass-derived furfural to cyclopentanone using Ru catalysts
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DOI：10.1039/c5gc01462j.png)
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Abstract
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The selective hydrogenation of furfural into cyclopentanone is an attractive transformation to advance in the sustainable synthesis of important chemicals from biomass. A supported Ru nanoparticle catalyst on an acidic MOF material (Ru/MIL-101) was designed for the highly active and selective conversion of furfural to cyclopentanone in aqueous media. Complete conversion of furfural with a selectivity higher than 96% was achieved within 2.5 h at 160 degrees C and 4.0 MPa H-2 pressure.
Keywords:
ALPHA,BETA-UNSATURATED ALDEHYDES
LEVULINIC ACID
LIQUID FUELS
CONVERSION
ADSORPTION
DEHYDRATION
CHEMICALS
XYLOSE
OXIDE
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