.png){kind=icon}
返回
Electronically Coupled 2D Polymer/MoS2 Heterostructures
.png){kind=icon}
OA
AI
DOI：10.1021/jacs.0c10151.png)
.png){kind=icon}
.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
Emergent quantum phenomena in electronically coupled two-dimensional heterostructures are central to next-generation optical, electronic, and quantum information applications. Tailoring electronic band gaps in coupled heterostructures would permit control of such phenomena and is the subject of significant research interest. Two-dimensional polymers (2DPs) offer a compelling route to tailored band structures through the selection of molecular constituents. However, despite the promise of synthetic flexibility and electronic design, fabrication of 2DPs that form electronically coupled 2D heterostructures remains an outstanding challenge. Here, we report the rational design and optimized synthesis of electronically coupled semiconducting 2DP/2D transition metal dichalcogenide van der Waals heterostructures, demonstrate direct exfoliation of the highly crystalline and oriented 2DP films down to a few nanometers, and present the first thickness-dependent study of 2DP/MoS2 heterostructures. Control over the 2DP layers reveals enhancement of the 2DP photoluminescence by two orders of magnitude in ultrathin sheets and an unexpected thickness-dependent modulation of the ultrafast excited state dynamics in the 2DP/MoS2 heterostructure. These results provide fundamental insight into the electronic structure of 2DPs and present a route to tune emergent quantum phenomena in 2DP hybrid van der Waals heterostructures.
Keyword:
COVALENT ORGANIC FRAMEWORKS
2-DIMENSIONAL POLYMER
THIN-FILMS
MONOLAYER
DYNAMICS
AI总结
对已上传原文的论文进行重点信息的提取，主要内容包括：简要概述、研究摘要、背景介绍、关键亮点、图文解析、展望与总结。
期刊
IF:
15.6
论文数:
20.0W
被引数:
60.2W
机构
引用论文
Lewis-Acid-Catalyzed Interfacial Polymerization of Covalent Organic Framework Films路易斯酸催化共价有机框架膜的界面聚合.png)
CHEMOAAI
CHEMIF19.6
OAAI分享收藏Covalent Organic Frameworks: Organic Chemistry Extended into Two and Three DimensionsTRENDS IN CHEMISTRY
TRENDS IN CHEMISTRYIF13.6
PREAI
分享收藏Investigation on microstructure and corrosion behavior of rolled Mg-1.5Zn-xCa-xCe alloy轧制Mg-1.5Zn-xCa-xCe合金的组织与腐蚀行为研究
PREAI
分享收藏分享收藏Covalent Organic Frameworks as a Platform for Multidimensional Polymerization共价有机框架作为多维聚合的平台ACS CENTRAL SCIENCEOAAI
ACS CENTRAL SCIENCEIF10.4
OAAI分享收藏
查看更多内容