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endo-Dibenzosexithiophene-Based Thienoquinoid: Impact of Fused-Ring Structure on the Open-Shell State
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DOI：10.1016/j.synthmet.2026.118171.png)
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Abstract
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• A fused-type thienoquinoid endo-DBST-CN featuring thienyl bridges was developed. • Ring fusion modulates the open-shell character and the singlet–triplet energy gap. • endo-DBST-CN shows an intense absorption band in the near-infrared region. • Organic field-effect transistors based on endo-DBST-CN exhibit n-type properties.
Keywords:
thienoquinoid
diradical
open-shell structure
organic field-effect transistors
near-infrared absorption
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