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Enhanced Mechanical and Thermal Properties of Transparent TPU Film Composites Based on Surface Modified Acid Activated Sepiolite Nanofibers

delete2026-07-02
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PRE
AI
K
Kaihang Zhou
X
Xiaoshuai Han
B
Bin He *
S
Shuijian He
G
Gaigai Duan *
姜韶华 cover
姜韶华 (Shaohua Jiang) *
DOI:10.1002/pola.70246delete
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Abstract

Abstract

En 中文
To tackle the issue of interfacial incompatibility between hydrophilic acid-activated sepiolite nanofibers (A-SEP) and hydrophobic thermoplastic polyurethane (TPU) matrices, this study utilizes methyl trimethoxysilane (MTMS) to perform surface hydrophobization modification on A-SEP. By silane coupling, hydrophobic methyl groups (CH3) are introduced to improve interfacial compatibility. MTMS modified-acid-activated sepiolite nanofibers/TPU (MSNF/TPU) nanocomposite films are prepared using the solution casting method, and systematic characterization reveals that: the mechanical properties of the modified composites (tensile strength, elongation at break, Young's modulus) are significantly enhanced, thermal stability (decomposition temperature, residual carbon rate) is improved, and the glass transition temperature (Tg) is adjustable. The transparency in the visible light spectrum is positively correlated with the state of fiber dispersion. This work offers a scalable interfacial engineering strategy for clay mineral-reinforced polymer composites.
Keywords:
acid-activated sepiolite nanofibers
interfacial compatibility
methyltrimethoxysilane modification
nanocomposite films
thermoplastic polyurethane

Journal

Journal of Polymer Science cover
Journal of Polymer Science
IF:
3.6
Papers:
2.2K
Citations:
6.4K

Organization

H
huzhou normal university
Scholars:
139
Papers: 47
Citations: 0
N
nanjing forestry university
Scholars:
3.9K
Papers: 1.4K
Citations: 0
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