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Experimental and theoretical study of intermolecular interactions in a silicon porphyrin
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DOI：10.1016/j.cplett.2026.142858.png)
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Abstract
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• The enthalpy of sublimation was determined to be 235(5) kJ/mol using the Knudsen effusion method. • A correlation was found between the energy of intermolecular interactions for etioporphyrins, estimated using theoretical calculations, and the enthalpy of sublimation. • It was established that the broadening of the Soret-band in solid films can be reproduced in theoretical simulated spectra of SiF2EtioP-I aggregates.
Keywords:
enthalpy of sublimation
intermolecular interactions
Knudsen effusion method
theoretical calculations
Soret-band broadening
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