.png){kind=icon}
返回
?-Extended Fullerenes with a Reactant Inside
.png){kind=icon}
PRE
AI
DOI：10.1021/jacs.2c12259.png)
.png){kind=icon}
原文求助.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
Fullerene-graphene hybrids potentially exhibit unprecedented properties owing to interactive communication between the two units through a linkage. However, most of their discrete molecular structures have been still undisclosed thus far. With the recent rise in the awareness of facile access to molecular nanocarbon hybrids, we showcase novel pi-extended fullerenes with a fused pyrazine or imidazole. Owing to the effective planar-curved pi-conjugation, their absorption coefficients significantly increased in the visible region. Curiously enough, during the formation of pi-extended fullerenes, an in situ generated NH3 molecule was spontaneously encapsulated inside the fullerene cavity. The NH3 molecule then underwent a timed orifice-expansion triggered by its sustained release. This is the first demonstration that fullerene captures a reactant inside, suggesting their potential usage for a sustained dosing and/or material delivery toward postfunctionalization of fullerene-graphene hybrids.
Keyword:
C-60 DERIVATIVES
WATER
AMMONIA
期刊
IF:
15.6
论文数:
20.0W
被引数:
60.2W
机构
引用论文
.png){kind=icon}
分享收藏Short and long-term carbon balance of bioenergy electricity production fueled by forest treatments
OAAI
OAAI分享收藏分享收藏分享收藏
查看更多内容