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Ferroic glasses

delete2017-10-12
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纪元超 (Yuanchao Ji)
王栋 封面图
王栋 (Dong Wang)
王雨 (Yu Wang)
周玉美 (Yumei Zhou)
薛德祯 (Dezhen Xue)
K
Kazuhiro Otsuka
W
Wang, Yunzhi *
X
Xiaobing Ren *
DOI:10.1038/s41524-017-0039-6delete
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摘要

摘要

En 中文
Ferroic glasses (strain glass, relaxor and cluster spin glass) refer to frozen disordered states in ferroic systems; they are conjugate states to the long-range ordered ferroic states-the ferroic crystals. Ferroic glasses exhibit unusual properties that are absent in ferroic crystals, such as slim hysteresis and gradual property changes over a wide temperature range. In addition to ferroic glasses and ferroic crystals, a third ferroic state, a glass-ferroic (i.e., a composite of ferroic glass and ferroic crystal), can be produced by the crystallization transition of ferroic glasses. It can have a superior property not possessed by its two components. These three classes of ferroic materials (ferroic crystal, ferroic glass and glass-ferroic) correspond to three transitions (ferroic phase transition, ferroic glass transition and crystallization transition of ferroic glass, respectively), as demonstrated in a generic temperature vs. defect-concentration phase diagram. Moreover, through constructing a phase field model, the microstructure evolution of three transitions and the phase diagram can be reproduced, which reveals the important role of point defects in the formation of ferroic glass and glass-ferroic. The phase diagram can be used to design various ferroic glasses and glass-ferroics that may exhibit unusual properties.
Keyword:
STRAIN GLASS
PHASE-TRANSITION
MECHANISM
TWEED
POLARIZATION
RANGE
STATE
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期刊

npj Computational Materials 封面图
npj Computational Materials
IF:
11.9
论文数:
2.4K
被引数:
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N
national institute for materials science
学者数:
9.5K
论文数: 1.3W
被引数: 28
X
xi'an jiaotong university
学者数:
9.3W
论文数: 6.7W
被引数: 75
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