.png){kind=icon}
返回
Five-coordinate iridium(III) complex with ΔΛ chirality
.png){kind=icon}
PRE
AI
DOI：10.1039/d1dt01960k.png)
.png){kind=icon}
原文求助.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
The coordinatively unsaturated bis-chelated iridium(III) complex, [Ir(2-Bubzq)(2)Cl] (2-BubzqH = 2-butyl-benzo[h]quinoline), denoted as complex 1, was obtained by reacting iridium(iii) trichloride with 2-BubzqH in a 1 : 2 molar ratio. The results were in contrast to the common view that a chlorine-bridged dimer, [Ir(L)(2)Cl](2) (L = bis-chelate ligand), is formed under the corresponding conditions. A single-crystal X-ray diffraction structural analysis revealed that complex 1 has a five-coordinate geometry with a distorted square pyramidal configuration. The optical resolution of complex 1 was measured chromatographically on a chiral column, yielding Delta and Lambda as enantiomers. The resolved enantiomers were stable enough against racemization in CDCl3 as confirmed by the vibrational circular dichroism measurements. Complex 1 reacted with carbon monoxide (CO) to give [Ir(2-Bubzq)(2)(CO)Cl] and with 1,10-phenanthroline (phen) to give [Ir(2-Bubzq)(2)(phen)]Cl within a minute with its absolute configuration (Delta Lambda chirality) maintained.
Keyword:
VIBRATIONAL CIRCULAR-DICHROISM
ORTHO-METALATED COMPLEXES
SINGLE-CRYSTAL
PHOSPHORESCENT
IR(III)
LIGANDS
AGENTS
BONDS
RED
期刊
IF:
3.3
论文数:
3.3W
被引数:
7.5W
机构
引用论文
Vibrational circular dichroism and single crystal X-Ray diffraction analyses of [Ir(bzq)2(phen)]+ (bzq = benzo[h]quinoline; phen=1,10-phenanthroline): absolute configuration and role of CH-π interaction in molecular packing.png)
DALTON TRANSACTIONS
DALTON TRANSACTIONSIF3.3
PREAI
分享收藏Judicious Design of Cationic, Cyclometalated Ir(III) Complexes for Photochemical Energy Conversion and Optoelectronics用于光化学能量转换和光电子学的阳离子，环金属化Ir(III) 配合物的明智设计
PREAI
分享收藏Understanding and predicting the orientation of heteroleptic phosphors in organic light-emitting materialsNATURE MATERIALS
OAAI
NATURE MATERIALSIF38.5
OAAI分享收藏Phosphorescent metal complexes as theranostic anticancer agents: combining imaging and therapy in a single moleculeCHEMICAL SCIENCEOAAI
CHEMICAL SCIENCEIF7.4
OAAI分享收藏Occupational bladder cancer: A cross section survey of previous employments, tasks and exposures matched to cancer phenotypes职业性膀胱癌: 与癌症表型匹配的先前工作，任务和暴露的横断面调查PLOS ONEOAAI
PLOS ONEIF0
OAAI分享收藏Iridium(III) phosphorescent complexes with dual stereogenic centers: single crystal, electronic circular dichroism evidence and circularly polarized luminescence propertiesDALTON TRANSACTIONSOAAI
DALTON TRANSACTIONSIF3.3
OAAI分享收藏Preparation of chiral-at-metal catalysts and their use in asymmetric photoredox chemistryNATURE PROTOCOLS
NATURE PROTOCOLSIF16
PREAI
分享收藏
查看更多内容