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Fluoro-Substituted Methyllithium Chemistry: External Quenching Method Using Flow Microreactors
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DOI：10.1002/anie.202003831.png)
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The external quenching method based on flow microreactors allows the generation and use of short-lived fluoro-substituted methyllithium reagents, such as fluoromethyllithium, fluoroiodomethyllithium, and fluoroiodostannylmethyllithium. Highly chemoselective reactions have been developed, opening new opportunities in the synthesis of fluorinated molecules using fluorinated organometallics.
Keyword:
amides
flow chemistry
lithium
microreactor
reactive intermediates
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53.0W
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Modular and Chemoselective Strategy for the Direct Access to α-Fluoroepoxides and Aziridines via the Addition of Fluoroiodomethyllithium to Carbonyl-Like Compounds通过将氟碘甲基锂添加到羰基类化合物中直接获得 α-氟环氧化合物和氮丙啶的模块化和化学选择性策略
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