.png){kind=icon}
返回
Functional Monolayers on a Superatomic Pegboard
.png){kind=icon}
PRE
AI
DOI：10.1021/jacs.3c01622.png)
.png){kind=icon}
原文求助.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
We advance the chemistry of apical chlorine substitution in the 2D superatomic semiconductor Re6Se8Cl2 to build functional and atomically precise monolayers on the surface of the 2D superatomic Re6Se8 substrate. We create a functional monolayer by installing surface (2,2 '-bipyridine)-4-sulfide (Sbpy) groups that chelate to catalytically active metal complexes. Through this reaction chemistry, we can create monolayers where we can control the distribution of catalytic sites. As a demonstration, we create highly active electrocatalysts for the oxygen evolution reaction using monolayers of cobalt(acetylacetonate)2bipyridine. We can further produce a series of catalysts by incorporating organic spacers in the functional monolayers. The structure and flexibility of the surface linkers can affect the catalytic performance, possibly by tuning the coupling between the functional monolayer and the superatomic substrate. These studies establish that the Re6Se8 sheet behaves as a chemical pegboard: a surface amenable to geometrically and chemically well-defined modification to yield functional monolayers, in this case catalytically active, that are atomically precise. This is an effective method to generate diverse families of functional nanomaterials.
Keyword:
MOS2
期刊
IF:
15.6
论文数:
20.0W
被引数:
60.2W
机构
引用论文
Intramolecular Proton Transfer Boosts Water Oxidation Catalyzed by a Ru ComplexRu配合物催化的分子内质子转移促进水氧化
OAAI
OAAI分享收藏
分享收藏Surface Modification of Black Phosphorus with Group 13 Lewis Acids for Ambient Protection and Electronic Tuning用第13族路易斯酸对黑磷进行表面改性，以进行环境保护和电子调谐
PREAI
分享收藏Why Do We Use the Materials and Operating Conditions We Use for Heterogeneous (Photo)Electrochemical Water Splitting?.png)
ACS CATALYSIS
ACS CATALYSISIF13.1
PREAI
分享收藏
查看更多内容