.png){kind=icon}
返回
Germanium(II) Dithiolene Complexes
.png){kind=icon}
OA
AI
DOI：10.1002/chem.202302258.png)
.png){kind=icon}
原文求助.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
The 1 : 2 reaction of the imidazole-based dithiolate (2) with GeCl2 center dot dioxane in THF/TMEDA gives 3, a TMEDA-complexed dithiolene-based germylene. Compound 3 is converted to monothiolate-complexed (5) and N-heterocyclic carbene-complexed (7) germanium(II) dithiolene complexes via Lewis base ligand exchange. A bis-dithiolene-based germylene (8), involving a 3c-4e S-Ge-S bond, has also been synthesized through controlled hydrolysis of 7. The bonding nature of 3, 5, and 8 was investigated by both experimental and theoretical methods. The chemistry at the germylene and dithiolene interface has rarely been explored. Here, we report a series of Lewis base-coordinated germanium(II) dithiolene complexes. Controlled hydrolysis of the carbene-coordinated germanium(II) dithiolene complex affords a dianionic bis-dithiolene-based germanium(II) species.image
Keyword:
carbenes
dithiolenes
germanides
germanium
germylenes
期刊
C
IF:
3.7
论文数:
3.9W
被引数:
9.6W
机构
引用论文
London dispersion forces in sterically crowded inorganic and organometallic molecules.png)
NATURE REVIEWS CHEMISTRY
NATURE REVIEWS CHEMISTRYIF51.7
PREAI
分享收藏Multiple bonding in heavier element compounds stabilized by bulky terphenyl LigandsINORGANIC CHEMISTRY
INORGANIC CHEMISTRYIF4.7
PREAI
分享收藏
查看更多内容