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Gradient nanostructuring via compositional means

delete2023-04-01
delete6
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OA
AI
A
Alejandro Barrios
J
James E. Nathaniel
J
Joseph M. Monti
Z
Zachary Milne
D
David P. Adams
K
Khalid Hattar
D
Douglas L. Medlin
R
Rémi Dingreville
B
Brad Boyce *
DOI:10.1016/j.actamat.2023.118733delete
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摘要

摘要

En 中文
Nanocrystalline metals are inherently unstable against thermal and mechanical stimuli, commonly resulting in significant grain growth. Also, while these metals exhibit substantial Hall-Petch strengthening, they tend to suffer from low ductility and fracture toughness. With regard to the grain growth problem, alloying el-ements have been employed to stabilize the microstructure through kinetic and/or thermodynamic mechanisms. And to address the ductility challenge, spatially -graded grain size distributions have been developed to facilitate heterogeneous deformation modes: high-strength at the surface and plastic deformation in the bulk. In the present work, we combine these two strategies and present a new methodology for the fabrication of gradient nanostructured metals via compositional means. We have demonstrated that annealing a compositionally stepwise Pt-Au film with a homogenous microstructure results in a film with a spatial microstructural gradient, exhibiting grains which can be twice as wide in the bulk compared to the outer surfaces. Additionally, phase-field modeling was employed for the comparison with experimental results and for further investigation of the competing mechanisms of Au diffusion and thermally induced grain growth. This fabri-cation method offers an alternative approach for developing the next generation of microstructurally stable gradient nanostructured films.
Keyword:
GRAIN-BOUNDARY SEGREGATION
THERMAL-STABILITY
MECHANICAL-PROPERTIES
FATIGUE RESISTANCE
STAINLESS-STEEL
SURFACE-LAYER
AU-PT
NANOCRYSTALLINE
COPPER
SIZE

期刊

Acta Materialia 封面图
Acta Materialia
IF:
9.3
论文数:
2.0W
被引数:
12.9W

机构

U
united states department of energy (doe)
学者数:
11.3W
论文数: 9.6W
被引数: 246
S
Sandia National Laboratories
学者数:
5.5K
论文数: 3.8K
被引数: 6.4K
引用论文

引用论文

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