.png){kind=icon}
返回
High-throughput computational solvent screening for lignocellulosic biomass processing
.png){kind=icon}
OA
AI
DOI：10.1016/j.cej.2022.139476.png)
.png){kind=icon}
原文求助.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
Lignocellulose is one of the most promising renewable bioresources for the production of chemicals. For sustainable and competitive biorefineries, effective valorization of all biomass fractions is crucial. However, current efforts in lignocellulose fractionation are limited by the use of either toxic or suboptimal solvents that do not always allow producing clean and homogeneous streams. Here, we present a computational screening approach that covers more than 8000 solvent candidates for the processing of lignocellulosic biomass. The automated screening identified highly effective, non-intuitive solvents based on physico-chemical properties, solubilities of the biomass fractions, and environmental, health and safety properties. Solubility experiments for the lignin and cellulose fraction confirmed the applicability of the proposed framework in biomass processing. In addition to the traditional lignin-first'' approaches, we identified solvents applicable for the complete dissolution of biomass. Furthermore, we elucidated particular structural patterns in solvents featuring high lignin solubility. The most promising solvents attained lignin solubilities of more than 33 wt%.
Keyword:
Lignocellulose
Biomass fractionation
Green solvents
Computer-aided solvent selection
COSMO-RS
期刊
IF:
13.2
论文数:
7.6W
被引数:
48.5W
机构
引用论文
Synthesis of soluble conjugated polymeric nanoparticles through heterogeneous Suzuki coupling reaction.png)
Polymer
PolymerIF0
PREAI
分享收藏Lignin Valorization through Catalytic Lignocellulose Fractionation: A Fundamental Platform for the Future Biorefinery通过催化木质纤维素分馏实现木质素增值: 未来生物精炼的基本平台CHEMSUSCHEM
CHEMSUSCHEMIF6.6
PREAI
分享收藏Effects of γ-valerolactone in hydrolysis of lignocellulosic biomass to monosaccharidesGREEN CHEMISTRY
OAAI
GREEN CHEMISTRYIF9.2
OAAI分享收藏Vibration spectrum of a two-soliton molecule in dipolar Bose–Einstein condensates双孤子分子在偶极玻色-爱因斯坦凝聚体中的振动谱
PREAI
分享收藏Isolation and biochemical characterization of underwater adhesives from diatoms来自硅藻的水下粘合剂的隔离和生化表征BiofoulingOAAI
BiofoulingIF0
OAAI分享收藏
查看更多内容