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How does lithium nitrate dissolve in a protic ionic liquid?
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DOI：10.1016/j.molliq.2014.08.007.png)
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The structural properties of a mixture of ethylammonium nitrate (EAN), a protic ionic liquid, and lithium nitrate are explored using X-ray diffraction and reverse Monte Carlo simulation. The system is characterised by the amphiphilically driven polar-apolar domains segregation that is peculiar of EAN, whilst the lithium ions distribute in the charged domains where they undergo a further level of self-segregation, prompting for a new ion salvation mechanism in amphiphilically nanostructured ionic liquids. (C) 2014 Elsevier B.V. All rights reserved.
Keyword:
Protic ionic liquids
X-ray diffraction
Self-assembly
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5.2
论文数:
2.5W
被引数:
9.0W
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