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Hydrazone-Linked Covalent Organic Frameworks
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DOI：10.1002/anie.202404941.png)
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摘要
En 中文
Hydrazone-linked covalent organic frameworks (COFs) with structural flexibility, heteroatomic sites, post-modification ability and high hydrolytic stability have attracted great attention from scientific community. Hydrazone-linked COFs, as a subclass of Schiff-base COFs, was firstly reported in 2011 by Yaghi's group and later witnessed prosperous development in various aspects. Their adjustable structures, precise pore channels and plentiful heteroatomic sites of hydrazone-linked structures possess much potential in diverse applications, for example, adsorption/separation, chemical sensing, catalysis and energy storage, etc. Up to date, the systematic reviews about the reported hydrazone-linked COFs are still rare. Therefore, in this review, we will summarize their preparation methods, characteristics and related applications, and discuss the opportunity or challenge of hydrazone-linked COFs. We hope this review could provide new insights about hydrazone-linked COFs for exploring more appealing functions or applications. This review provides an introduction on the recent progresses made in the field of hydrazone-linked COFs for various applications including adsorption/separation, catalysis, chemical sensing and energy storage. image
Keyword:
covalent organic frameworks
hydrazone linkage
structural flexibility
hydrolytic stability
heteroatomic sites
期刊
IF:
16.9
论文数:
5.7W
被引数:
53.0W
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