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Kinetic and thermodynamic analysis of wooden crayon shavings (WCS) non-isothermal pyrolysis based on enthalpy-entropy compensation
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DOI：10.1016/j.tca.2026.180389.png)
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Abstract
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• Comprehensive TG-DTG, SEM-EDS and elemental analyses clearly reveal WCS heterogeneity. • Isoconversional kinetics show strong Ea(α) variation confirming a multistep pyrolysis. • Lognormal deconvolution resolves five overlapping DTG peaks with excellent accuracy. • Compensation analysis confirms genuine physicochemical origin of WCS pyrolysis. • Compensation showed advances structural disordering in polymer-to-char transformation.
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