.png){kind=icon}
返回
Layer-by-Layer Assembled Solid Polymer Electrolyte for Electrochromic Devices
.png){kind=icon}
PRE
AI
DOI：10.1021/cm103572q.png)
.png){kind=icon}
原文求助.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
A new solid polymer electrolyte film fabricated by layer-by-layer (LbL) assembly is presented. The electrolyte film consists of four interbonding layers per deposition cycle, which combines electrostatic and hydrogen bonding in the same structure. Linear poly(ethylene imine) (LPEI) and poly(ethylene oxide) (PEO) are used to enhance the dissolution of lithium salt and the ionic transport through segmental motions of polymer chains. Characterization of film structure and growth shows good incorporation of electrostatic and hydrogen bonding, because of the versatile control of the ionization of poly(acrylic acid) (PAA), which serves as a bridging molecule. Ionic conductivity values, as described by the Vogel-Fulcher-Tammann equation, are found to be above 10(-5) S/cm for the dried electrolyte at room temperature and moderate humidity (52%RH). Thermal analysis reveals two competing processes, namely, cross-linking of LPEl and PAA to form an amide compound and segregation of PEO crystalline phase, which results in a moderate reduction of conductivity in the electrolyte after heating. Demonstration of solid electrochromic devices using the LbL-assembled polymer electrolyte is presented in both transmission and reflection mode with a modulation of 30%-40% in the visible and near-infrared range. The successful fabrication of the LbL-assembled electrolytes enables the realization of completely flexible, polymeric, and solid electrochromic devices.
Keyword:
layer-by-layer assembly
solid polymer electrolyte
electrochromic device
AI总结
对已上传原文的论文进行重点信息的提取，主要内容包括：简要概述、研究摘要、背景介绍、关键亮点、图文解析、展望与总结。
期刊
IF:
7
论文数:
2.8W
被引数:
11.4W
机构
引用论文
Layer-by-Layer Hydrogen-Bonded Polymer Films: From Fundamentals to Applications.png)
ADVANCED MATERIALS
ADVANCED MATERIALSIF26.8
PREAI
分享收藏Crystalline and amorphous phases in the poly(ethylene oxide)-LiCF3SO3 system聚 (环氧乙烷)-LiCF3SO3系统中的结晶相和非晶相MACROMOLECULES
MACROMOLECULESIF5.2
PREAI
分享收藏Ionic effects of sodium chloride on the templated deposition of polyelectrolytes using layer-by-layer ionic assemblyMACROMOLECULES
MACROMOLECULESIF5.2
PREAI
分享收藏
Synthesis of passivating, nylon-like coatings through cross-linking of ultrathin polyelectrolyte films通过超薄聚电解质膜的交联合成钝化的尼龙状涂层
PREAI
分享收藏
查看更多内容