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Local mode behavior in H2Te
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DOI：10.1063/1.2768949.png)
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A high-resolution spectrum of hydrogen telluride (H2Te) was recorded in the 4050-7000 cm(-1) region. Two bands could be observed at 4900 and 5980 cm(-1) and were assigned as the (20(+/-),1)<-(00(+),0) and (30(+/-),0)<-(00(+),0) bands, respectively. Rotational transitions of the two bands were assigned for the most abundant (H2Te)-Te-130 and (H2Te)-Te-128 isotopic species. Line position analyses were carried out to investigate a possible local mode behavior. For the first time we found in H2Te strong experimental evidence for such a behavior for the higher-lying band as its two upper vibrational states are only 0.027 and 0.032 cm(-1) apart for the (H2Te)-Te-130 and (H2Te)-Te-128 isotopic species, respectively. (C) 2007 American Institute of Physics.
Keyword:
OVERTONE BAND SYSTEM
ELECTRONIC GROUND-STATE
ENERGY-LEVEL STRUCTURE
HIGH-RESOLUTION
SYMMETRICAL HYDRIDES
HYDROGEN TELLURIDE
VIBRATIONAL-STATES
H-2 S-32
MU-M
SPECTRUM
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3.1
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7.2W
被引数:
23.2W
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