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Long-range extended chains arising from polymerization-driven spontaneous assembly
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DOI：10.1126/science.aef1777.png)
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Abstract
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Coupling of noncovalent interactions between chains to monomer addition in solution can form long, highly conductive polymer nanoribbons with ordered backbones. Chen et al. showed that n-polybenzodifurandione nanoribbons grew spontaneously when monomers transferred electrons to the growing polymer, which led to n-type doping and also activated the monomer for oxidative polymerization. The conductivity of thin films of the aligned nanoribbons (more than 10⁴ Siemens per centimeter) rivaled that of metals. —Phil Szuromi
Journal
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45.8
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1.4W
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