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Low-melting, ether-functionalised lithium salts for enhanced ion transport in molten salt electrolytes
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DOI:10.1039/d5ya00246j.png)
Abstract
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We report ether-functionalised lithium salts as molten salt electrolytes for Li-ion batteries. Flexible ether chains in asymmetric anions suppress crystallinity and promote nano-segregation, lowering melting points below 100 degrees C. In the molten state, they deliver high ionic conductivity and near-unity Li+ transference numbers, establishing a molecular design principle for high-performance, solvent-free electrolytes for next-generation energy storage.
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