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Matrix-Directed Mineralization for Bulk Structural Materials

delete2022-09-26
delete34
PRE
AI
茅
茅瓅波 (Li‐Bo Mao)
Y
Yu‐Feng Meng
X
Xiang‐Sen Meng
B
Bo Yang
Y
Yulu Yang
Y
Yujie Lu
Z
Zhong-Yuan Yang
L
Li‐Mei Shang
俞
俞书宏 (Shu‐Hong Yu) *
DOI:10.1021/jacs.2c07296delete
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摘要

摘要

En 中文
Mineral-based bulk structural materials (MBSMs) are known for their long history and extensive range of usage. The inherent brittleness of minerals poses a major problem to the performance of MBSMs. To overcome this problem, design principles have been extracted from natural biominerals, in which the extraordinary mechanical performance is achieved via the hierarchical organization of minerals and organics. Nevertheless, precise and efficient fabrication of MBSMs with bioinspired hierarchical structures under mild conditions has long been a big challenge. This Perspective provides a panoramic view of an emerging fabrication strategy, matrix-directed mineralization, which imitates the in vivo growth of some biominerals. The advantages of the strategy are revealed by comparatively analyzing the conventional fabrication techniques of artificial hierarchically structured MBSMs and the biomineral growth processes. By introducing recent advances, we demonstrate that this strategy can be used to fabricate artificial MBSMs with hierarchical structures. Particular attention is paid to the mass transport and the precursors that are involved in the mineralization process. We hope this Perspective can provide some inspiring viewpoints on the importance of biomimetic mineralization in material fabrication and thereby spur the biomimetic fabrication of high-performance MBSMs.
Keyword:
SELF-ASSEMBLED MONOLAYERS
WALL CARBON NANOTUBES
CRYSTAL NUCLEATION
CALCIUM-CARBONATE
NACREOUS LAYER
GROWTH
COMPOSITES
HYDROGELS
NANOCOMPOSITES
FABRICATION

期刊

Journal of the American Chemical Society 封面图
Journal of the American Chemical Society
IF:
15.6
论文数:
20.0W
被引数:
60.2W

机构

C
chinese academy of sciences
学者数:
56.7W
论文数: 45.0W
被引数: 704
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