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Medium-density amorphous ice

delete2023-01-01
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OA
AI
A
Alexander Rosu-Finsen
M
Michael B. Davies
A
Alfred Amon
H
Han Wu
A
Andrea Sella
A
Angelos Michaelides
C
Christoph G. Salzmann
DOI:10.1126/science.abq2105delete
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摘要

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En 中文
Amorphous ices govern a range of cosmological processes and are potentially key materials for explaining the anomalies of liquid water. A substantial density gap between low-density and high-density amorphous ice with liquid water in the middle is a cornerstone of our current understanding of water. However, we show that ball milling “ordinary” ice I h at low temperature gives a structurally distinct medium-density amorphous ice (MDA) within this density gap. These results raise the possibility that MDA is the true glassy state of liquid water or alternatively a heavily sheared crystalline state. Notably, the compression of MDA at low temperature leads to a sharp increase of its recrystallization enthalpy, highlighting that H 2 O can be a high-energy geophysical material.
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