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Melanin and Light

delete2024-10-31
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OA
AI
A
Arianna Menichetti
D
Dario Mordini
M
Marco Montalti *
DOI:10.1002/chem.202400461delete
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摘要

摘要

En 中文
Melanin is responsible, in Nature, for photoprotection, for this reason it is expected to be poorly photoreactive. However, the photo-reactivity of melanin and related materials is well documented. Here we discuss some relevant recent examples to demonstrate that, indeed, the actual mechanism of interaction of melanin with light is complex and still not completely understood. Photochemical and photothermal processes are involved, giving a contribution that strongly depends on light wavelength and intensity. Moreover, some interesting experiments demonstrated that photochemical reactivity of melanin related compounds is likely to be indirect, in the sense that the effect of light is to increase the number of radical species rather than creating photoreactive excited state. These suggestions open-up new perspectives in the interpretation of the role of melanin in photoprotection and in the design of new melanin based photoactive materials for energy conversion, environmental remediation, and nanomedicine. Further complication is given by the role of atmospheric oxygen and humidity in the photoinduced processes. Beside this complexity of behavior makes it difficult a systematic understanding of the interaction of melanin with light, it surely strongly contributes to make the properties of melanin and related materials unique.
Keyword:
Nanoparticles
Polydopamine
Biocompatibility
Photochemistry
Photothermal

期刊

C
Chemistry-A European Journal
IF:
3.7
论文数:
3.9W
被引数:
9.6W

机构

U
University of Bologna
学者数:
4.5W
论文数: 3.8W
被引数: 4.1W
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