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Melt crystallization of the odd–even polyamide nylon 7,10: kinetics, spherulitic morphology and molecular orientation
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DOI：10.1016/j.polymer.2026.130411.png)
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Abstract
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• Melt crystallization of nylon 7,10 is strongly influenced by temperature and molecular parameters • Distinct spherulitic morphologies develop within narrow crystallization windows • Molecular weight and polydispersity strongly affect crystallization kinetics • Low-molecular-weight species hinder crystal growth through interfacial effects • FTIR microspectroscopy reveals anisotropic organization in birefringent spherulites
Keywords:
Odd–even polyamides
hydrogen bonding
melt crystallization
banded spherulites
lamellar morphology
infrared microspectroscopy
crystallization kinetics
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