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Methanol-detection by acrylate-based composite polymer film actuation

delete2026-05-23
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R
Riccardo Castagna *
C
Cristiano Riminesi
D
Daniele E. Lucchetta
F
Fabrizio Papa
G
Gautam Singh
M
Mario Da Prada
A
Andrea Di Donato *
DOI:10.1016/j.optmat.2026.117946delete
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Abstract

Abstract

En 中文
We demonstrate a proof-of-concept approach for VOC detection based on the mechanical bending of acrylatebased composite polymer films. Under ambient conditions, methanol vapours induce a rapid and reversible defor-mation of the film, which is optically observable and quantitatively described through a viscoelastic three-parameter solid model coupled to pseudo-first-order adsorption kinetics. The bending response differs markedly between methanol, water, and mixed vapours, revealing a strong dependence on sur-face adsorption dynamics. The acrylate backbone is identified as the active sensing layer, capable of transducing molecular interactions into macroscopic deflection. These findings establish acrylate polymers as a simple, low-cost platform for passive VOC-responsive materials and highlight their potential for future development into calibrated sensing devices.
Keywords:
Volatile organic compounds (VOCs)
Polymer-film actuator
Sensors
Photo-mobile polymer films
PMPs
Methanol-responsive bending
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Optical Materials cover
Optical Materials
IF:
4.2
Papers:
1.7W
Citations:
3.4W

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M
Marche Polytechnic University
Scholars:
1.1W
Papers: 9.4K
Citations: 1.1W
A
amity university noida
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3.5K
Papers: 2.8K
Citations: 6
C
consiglio nazionale delle ricerche (cnr)
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6.2W
Papers: 5.7W
Citations: 48
U
University of Camerino
Scholars:
4.1K
Papers: 3.4K
Citations: 2
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