.png){kind=icon}
返回
Mixed polyoxyanion cathode materials
.png){kind=icon}
PRE
AI
DOI：10.1016/j.ensm.2021.08.016.png)
.png){kind=icon}
原文求助.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
The discovery of new chemistries superior to modern lithium intercalation cathodes is of great scientific and technological importance. The cathodes play a key role in the performance of lithium-ion batteries (LIB). While layered oxide cathodes deliver high capacity, polyanion compounds show structural stability, operational safety, tunable redox potentials, etc. The growing applications of LIBs, along with a decrease in the abundance of Li sources and an increase in their cost, have led to postlithium-battery era, where sodium-ion batteries (SIBs) are a suitable alternative for full/partial substitutions of LIBs and are most promising for large-scale applications, independent of size/weight restriction, in particular, for stationary energy storage devices. However, the number of known Na-based cathode materials with energy density close to Li-based materials is limited that suggests searching for new intercalation materials. Recently, studies of mixed polyoxyanion cathodes have been initiated with the aim of further enriching the chemistry by combining two types of polyoxyanion units (so called 'anionic engineering'). This cathode family may open new framework-structured insertion materials, capable of multiple electron redox reaction and appropriate potential for high voltage operation, thereby increasing energy density. In this review, we report on a series of new mixed polyoxyanion compounds for LIBs and SIBs. A comprehensive list of these materials along with their crystal structure, synthesis methods, and electrochemical characteristics is provided.
Keyword:
Mixed polyoxyanion cathode materials
Anionic engineering
Lithium-ion batteries
Sodium-ion batteries
AI总结
对已上传原文的论文进行重点信息的提取，主要内容包括：简要概述、研究摘要、背景介绍、关键亮点、图文解析、展望与总结。
期刊
IF:
20.2
论文数:
5.7K
被引数:
6.3W
机构
引用论文
Theoretical and experimental study of reversible intercalation of Li ions in the Jarosite NaFe3(SO4)2(OH)6 structure锂离子在黄钾铁矾NaFe3(SO4)2(OH)6结构中可逆插层的理论和实验研究.png)
ELECTROCHIMICA ACTA
ELECTROCHIMICA ACTAIF5.6
PREAI
分享收藏The first investigation of the synthetic mechanism and lithium intercalation chemistry of Li9Fe3(P2O7)3(PO4)2/C as cathode material for lithium ion batteriesDALTON TRANSACTIONS
DALTON TRANSACTIONSIF3.3
PREAI
分享收藏Nanosheets of Earth-Abundant Jarosite as Novel Anodes for High-Rate and Long-Life Lithium-Ion Batteries富含地球的金黄矿纳米片作为高倍率和长寿命锂离子电池的新型阳极
PREAI
分享收藏Novel mixed polyanions lithium-ion battery cathode materials predicted by high-throughput ab initio computations通过高通量从头算预测的新型混合聚阴离子锂离子电池正极材料
PREAI
分享收藏Cathode Properties of Na3FePO4CO3 Prepared by the Mechanical Ball Milling Method for Na-ion Batteries通过机械球磨法制备的Na3FePO4CO3用于钠离子电池的阴极性能SCIENTIFIC REPORTS
OAAI
SCIENTIFIC REPORTSIF3.9
OAAI分享收藏Ball mill assisted synthesis of Na3MnCO3PO4 nanoparticles anchored on reduced graphene oxide for sodium ion battery cathodes球磨辅助合成Na3MnCO3PO4纳米粒子锚定在还原氧化石墨烯上的钠离子电池正极ELECTROCHIMICA ACTA
ELECTROCHIMICA ACTAIF5.6
PREAI
分享收藏Thermal and structural instability of sodium-iron carbonophosphate ball milled with carbon碳球磨的碳磷酸铁钠的热和结构不稳定性ELECTROCHIMICA ACTA
ELECTROCHIMICA ACTAIF5.6
PREAI
分享收藏
查看更多内容